Unlocking single molecule magnetism: a supramolecular strategy for isolating neutral MnIII salen-type dimer in crystalline environments
Yuri Kyoya,
Kiyonori Takahashi,
Wataru Kosaka
et al.
Abstract:In [Mn(5-MeOsalen)(Cl)]2(dibenzo[24]crown-8), dibenzo[24]-crown-8 formed a supramolecule via multi-point interactions with the [Mn(5-MeOsalen)(Cl)] dimer. The dimer was magnetically isolated with ST = 4 and weak interdimer magnetic interactions. The crystal exhibited...
Three novel Mn(iii) vanhd complexes, namely [Mn(o-vanhd)(N3−)(H2O)]·CH3OH (1), [Mn(o-vanhd)(NCS−)(H2O)]·2CH3CN (2), and [Mn(o-vanhd)(H2O)]·ClO4·H2O (3), have been successfully synthesized using compartmental ligands paired with ancillary ligands.
Three novel Mn(iii) vanhd complexes, namely [Mn(o-vanhd)(N3−)(H2O)]·CH3OH (1), [Mn(o-vanhd)(NCS−)(H2O)]·2CH3CN (2), and [Mn(o-vanhd)(H2O)]·ClO4·H2O (3), have been successfully synthesized using compartmental ligands paired with ancillary ligands.
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