Unlocking same‐sign CPL: solvent effects on spectral form and racemisation kinetics in nine‐coordinate chiral europium(III) complexes
Davide F. De Rosa,
Matthieu Starck,
David Parker
et al.
Abstract:Understanding the factors that shape the circularly polarised luminescence (CPL) emission profiles of europium(III)‐based CPL emitters to have specific sign properties, e. g. monosignate individual CPL transitions, is key to design novel complexes for applications ranging from advanced security inks to bio‐probes for live cell imaging. In order to correlate structure and spectral characteristics, a photophysical and kinetic investigation has been conducted on a series of coordinatively saturated nine‐coordinat… Show more
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