Universality of Meyer-Neldel Compensation rule (MNCR): Case study of thermally assisted a.c. conduction after laser irradiation

Kumar, Amit; Mehta, N.

doi:10.1016/j.jpcs.2018.05.008

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Cited by 6 publications

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“…diffusion coefficients [14][15][16][17], polymer relaxation frequencies [18], silicon annealing rates [19], crystal growth rates [20], semiconductor thermal electron emission rates [21] or solid-state electrical conductivities [22][23][24][25][26][27][28]) and even food technology [29]. However, its acceptance as a physically meaningful phenomenon remains considerably controversial [30][31][32][33][34].…”

Section: Introductionmentioning

confidence: 99%

Interdependence of the Hammett and isokinetic relationships: a numerical simulation approach

Perez‐Benito

Clavero-Masana

2021

Monatsh Chem

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Many homologous reaction series present linear correlations between the enthalpy ( o ,i H   ) and entropy ( o ,i S  ) of activation (kinetic compensation effect), the slope being the isokinetic temperature of the series (T iso ), so that at T = T iso all the reactions of the family share the same value of the rate constant. S   vs. i  plots, are all indicative of false isokinetic relationships, highly contaminated by the statistical correlation between the enthalpy and entropy experimental errors.

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