Universal inter-molecular radical transfer reactions on metal surfaces
Junbo Wang,
Kaifeng Niu,
Huaming Zhu
et al.
Abstract:On-surface synthesis provides tools to prepare low-dimensional supramolecular structures. Traditionally, reactive radicals are a class of single-electron species, serving as exceptional electron-withdrawing groups. On metal surfaces, however, such species are affected by conduction band screening effects that may even quench their unpaired electron characteristics. As a result, radicals are expected to be less active, and reactions catalyzed by surface-stabilized radicals are rarely reported. Herein, we descri… Show more
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