better uniformity. [20] While for URS mode, owing to the single polarity operation, it allows a diode as the selector in crossbar arrays to settle the sneak-path issue. [21] And this passive crossbar array with one diode-one resistor (1D1R) structure offers advantages in achieving the highest integration density of 4F 2 [22] as well as enables simplified peripheral control elements to support large-scale integrated circuits. [23] To date, reliable BRS and URS behaviors have been observed in a wide variety of materials, including binary metal oxides HfO 2 , TaO x , ZnO, WO x , NiO, etc. [24][25][26][27][28][29] Beneficial to high density data storage, multilevel switchings have also been demonstrated in both BRS [24,25,30,31] and URS [27,32] devices, as well as devices with atypical coexistent BRS and URS. [33,34] Furthermore, in order to catch the speed of the microprocessor working in gigahertz lockstep, sub-nanosecond operation speed is required for nextgeneration memories, which has been obtained in BRS devices with binary memory states but was not achieved in any multilevel RRAMs. For example, operation speeds as fast as 300 and 100 ps were achieved in HfO x and Pt-SiO 2 based BRS RRAMs, respectively, [35][36][37] while the reliable multilevel control in BRS RRAMs was only obtained with operation speed of dozens or even hundreds of nanoseconds. [24,27,31,32] By comparison, no sub-nanosecond multilevel switchings were reported in URS RRAM. Therefore, it will be interesting to study the sub-nanosecond operating ability in a URS device, in which a typical high off/on resistance ratio may be able to host multilevel resistance states with ultrafast operation speed.As an important magnetic insulator, yttrium iron garnet Y 3 Fe 5 O 12 (YIG) has been used in microwave, acoustic, optical, and magneto-optical applications, as well as spintronic devices owing to its low damping constant and insulating ferromagnetic nature. [38][39][40] Besides the well-known magneto-optical memory applications for YIG, early in 1970, Bullock et al. found a repeatable URS behavior in Si-doped YIG crystal. [41] This discovery demonstrates the possible application of YIG as an RRAM device, but no further resistive switching investigations were carried out since then. The high performance of the Au/YIG/n-Si RRAM cells was herein reported with sub-nanosecond switching speed, high off/on resistance ratio, well endurance, and reliable retention at both room temperature and 85 °C. Multi resistance states were achieved during the DC voltage sweep as well as ultrafast pulse operation. Furthermore, YIG-based RRAM is fabricated on silicon substrate, further illustrating its promising potential for commercial application in memories.Resistive random access memory (RRAM) with ultrafast and multilevel switching is extremely promising for next-generation nonvolatile memory. Here, ultrafast unipolar resistive switchings (≈540 ps) with high off/on resistance ratio (≈10 4 ) are obtained in yttrium iron garnet Y 3 Fe 5 O 12 (YIG)-based resistive memory on ...