Online experimental systems that include remote and virtual experiments based on the Internet has become a new form of experiment in engineering education. This paper proposes a virtual experiment for the complex process control system. It is based on the networked control system laboratory (NCSLab), which provides a reliable framework for virtual thermal experiment. Taking the combustion system of 1000 MW ultra-supercritical coal-fired once-through boiler-turbine units as an example, the framework and the implementation process of the online system are given in this paper. A new presentation form for complex processes control experiment is provided, which could be a solution for simulating physical experimental equipment in virtual environments. The potential danger in practical experiments could be avoided. Additionally, the real-time operation for complex control systems could be presented in a 3D scene. Meanwhile, the flexibility and efficiency could be increased in engineering experimental education. Moreover, using the experiment evaluation method, the references and feedback for teaching and assessment are provided in this paper.