Abstract:Unidirectional double-hydrogen
(2H) and triple-hydrogen (3H) rearrangement
reactions occur upon electron-ionization-induced fragmentation of trans-2-(4-N,N-dimethylaminobenzyl)-1-indanol
(1), trans-2-(4-methoxybenzyl)-1-indanol
(2), 4-(4-N,N-dimethylaminophenyl)-2-butanol
(3), and related compounds, as reported some 35 years
ago (Kuck, D.; Filges, U. Org. Mass Spectrom.
1988, 23, 643–653). These unusual
intramolecular redox processes were found to dominate the mass spectra
of long-lived, metastable ions. The p… Show more
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