In Lorraine, flooding of the iron mines leads to a degradation of groundwater quality. Based on a global approach, a numerical simulator has been built that can reproduce and predict the evolution of water quality at the overflow point of the mining basin. In order to specify the spatial distribution of these pollutant concentrations, a new model has been developed. The basin is represented as a network of homogeneous reservoirs. Although encouraging, the results show the need to specify the spatial organisation of water flow in order to reproduce the pollutant concentrations in the different monitored wells.