Abstract:Introducing oligomeric or polymeric units into metal-organic frameworks (MOFs) can result in composites that have significantly improved properties when compared to the individual MOF or polymer building blocks. With such synergy in mind, this work presents the design of a novel MOF/polyazoamine support that is used to stabilize Pd NPs. The resulting composite catalyst, tested in the reductive amination of levulinic acid, is found to have a markedly improved lifetime when compared to just the MOF or polymer su… Show more
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