Understanding the Interaction Mechanism between Elemental Selenium and Ferric Hydroxide in Wastewater Treatment

Abstract

The conversion of selenium oxyanions to elemental selenium (Se0) of low solubility and bioavailability is an effective industrial approach for selenium management in wastewater treatment. The generated Se0 particles require further treatment with coagulants such as ferric ions to facilitate the precipitation of Se0 particles. In this work, the settling of Se0 particles in simulated wastewater was investigated with amorphous ferric hydroxide (Fe­(OH)3) as a coagulant prepared from hydrolysis of ferric chloride. The effects of ferric ion dosage, water composition, and pH on the Se0 removal percentage were investigated. The surface properties, i.e., ζ potential and morphology, were characterized, which influenced the interactions between Se0 and Fe­(OH)3. The forces acting between Se0 and Fe­(OH)3 surfaces were directly measured, for the first time, using atomic force microscopy (AFM). The water composition and pH had a significant effect on the adhesion force. In simulated wastewater, the adhesion force generally increased with pH, suggesting that the adsorption of Ca2+ and Mg2+ on Fe­(OH)3 surface increased with pH, which enhanced the adhesion. Interestingly, long-range pull-off forces and sawtooth patterns were observed on the retraction force–separation curves, which were attributed to the stretching of Fe­(OH)3 particle aggregates or chains during separation. Bulk settling tests showed that the best Se0 removal performance of Fe­(OH)3 was found to be around pH 8, which was because the largest amount of Fe­(OH)3 precipitates was found around this pH. The results indicate that the Fe­(OH)3 solubility as well as the related intermolecular and surface forces play the predominant role in determining the Se0 removal performance of the ferric coagulant. This work, for the first time, revealed the interaction mechanisms of Se0 particle and amorphous Fe­(OH)3, providing useful insights on the performance of ferric coagulants on Se0 particle removal from wastewater under various solution conditions. The experimental approach used in this work can be readily extended to other water treatment systems and processes such as polymer flocculation.

Mechanism of galvanic reduction of selenate oxyanions and surface immobilization by nano zero-valent iron aggregates under anaerobic conditions: towards high electron efficiency

“…No evidence of distinct Se nanoparticles forming away from the nZVI can be found like what happens in other chemical or biological reduction systems which pose environmental hazards and demand post-reduction treatments like coagulation. 19 In other words not only soluble Se( vi ) is removed/eliminated down to <10 μg L −1 but also it is fully immobilized by the nZVI aggregates. The full association of Se with nZVI by deposition on its surface is confirmed with the help of an EDS elemental line profile (the orange straight line in Fig.…”

“…In Fig. 6 19 In other words not only soluble SeIJVI) is removed/eliminated down to <10 μg L −1 but also it is fully immobilized by the nZVI aggregates. The full association of Se with nZVI by deposition on its surface is confirmed with the help of an EDS elemental line profile (the orange straight line in Fig.…”

“…2,12 These vary from adsorption and co-precipitation (involving ferrihydrite, iron oxides/hydroxides FeOOH, Fe 3 O 4 , Fe 2 O 3 , FeIJOH) 3 , aluminum oxides 13 or carbon 2 ) and ion exchange 2,14 to TiO 2 -assisted photocatalysis 15,16 and biological 17 or chemical 18 reduction usually accompanied by coagulation. 19 Galvanic reduction with zero-valent iron (ZVI) 20,21 is another process that has been considered in treating Seladen wastewater or soil decontamination but again this is mostly successful with selenite reduction. 22,23 This system is analogous to the corrosion of iron 20 with the surface of iron comprising anodic (Fe → Fe 2+ + 2e − ) and cathodic sites (Se 4+ + 4e − → Se 0 ) covered by corrosion products (hydrous Fe(II)/ Fe(III) oxides).…”

“…2,12 These vary from adsorption and co-precipitation (involving ferrihydrite, iron oxides/hydroxides FeOOH, Fe 3 O 4 , Fe 2 O 3 , Fe(OH) 3 , aluminum oxides 13 or carbon 2 ) and ion exchange 2,14 to TiO 2 -assisted photocatalysis 15,16 and biological 17 or chemical 18 reduction usually accompanied by coagulation. 19…”

Probing the In Situ Redox Behavior of Selenium on a Pyrite Surface by Scanning Electrochemical Microscopy

“…It is also rational that the adsorption of selenium on pyrite surface is on the hydrated iron sites, as previous studies on the removal of selenium from water through adsorption suggested the efficient adsorption by iron oxide/hydroxide. 37,38 The SECM results suggest that the electrodeposited selenium is associated with iron. However, in the case of adsorbed Se-pyrite, there is no detected iron associated with the release of selenium, and sulfur is oxidized as a result of selenium adsorption.…”