Efficient and sustainable urban mobility is critical for contemporary cities, and understanding the factors influencing modal choices is essential for addressing transportation challenges in metropolitan areas. This study focuses on the Porto Metropolitan Area (AMP) in Portugal and aims to gain insights into these factors. Using data from the last mobility survey (IMob) conducted in 2017, a multinomial logit (MNL) model is used to analyze individual modal choices amongst private motorized vehicles (PMVs), public transport (PT), and active modes (AMs). The findings unveiled that demographic, socioeconomic, and travel-related characteristics substantially influence individual modal choices within the studied area. Moreover, probability scenarios highlight the importance of financial considerations, environmental consciousness, and accessibility to public transport in promoting sustainable transportation options. These insights have significant implications for policymakers and stakeholders involved in urban planning and transportation management. This study contributes to the literature by providing valuable insights into individuals’ transportation preferences and behaviors, facilitating decision-making based on evidence for infrastructure improvements and targeted interventions. By promoting sustainable transportation alternatives and reducing reliance on PMVs, this study aims to enhance the livability and sustainability of the AMP, aligning with long-term sustainability goals.