1999
DOI: 10.1002/(sici)1521-3749(199907)625:7<1193::aid-zaac1193>3.0.co;2-l
|View full text |Cite
|
Sign up to set email alerts
|

Undecaborates M2[B11H11]: Facile Synthesis, Crystal Structure, and Reactions

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

2
45
0
2

Year Published

2000
2000
2018
2018

Publication Types

Select...
6

Relationship

2
4

Authors

Journals

citations
Cited by 50 publications
(49 citation statements)
references
References 15 publications
2
45
0
2
Order By: Relevance
“…More recent investigations of these clusters have resulted in the X-ray crystallographic analysis of the structures as well as further functionalization, however the halogenated derivatives remain the only perfunctionalized clusters in the B n H n (n = 7–11) series to date. 57,6164 …”
Section: Synthesis Of Perfunctionalized Boron Clustersmentioning
confidence: 99%
“…More recent investigations of these clusters have resulted in the X-ray crystallographic analysis of the structures as well as further functionalization, however the halogenated derivatives remain the only perfunctionalized clusters in the B n H n (n = 7–11) series to date. 57,6164 …”
Section: Synthesis Of Perfunctionalized Boron Clustersmentioning
confidence: 99%
“…2; note that we use a numbering system for B, which is derived from A, Fig. The geometric data were used for a GIAO computation of the 1 H and 11 B NMR shifts of C. The results are compared to the data, which had been measured in CD 2 Cl 2 at ±40°C [9] in Table 2. 2).…”
Section: Calculated Structure and Nmr Spectra Of [B 11 H 12 ] ±mentioning
confidence: 99%
“…We had proposed, that a proton attacks [B 11 H 11 ] 2± at the bond 2±4 of B 1 , which connects the vertices of lowest connectivity (c = 4) [9]. The obtained anion [B 11 H 12 ] ± is stable in solution up to ±10°C and ± in contrast to the conjugate base ± does not exhibit skeletal mobility, according to the NMR spectra.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…The second principal type of carbaalane has a closo-configuration on the basis of its structure and electron count (3; Scheme 1) and is a remarkable analogue of the closo-borate anion [B 11 H 11 ] 2Ϫ . [5] The bonding situation in the carbaalanes has been studied by quantum-chemical calculations. [4] They revealed a delocalized multi-centre bonding with only weak direct AlϪAl interactions.…”
Section: Introductionmentioning
confidence: 99%