2021
DOI: 10.1039/d1ce00094b
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Uncovering new transition metal Zintl phases by cation substitution: the crystal chemistry of Ca3CuGe3 and Ca2+nMnxAg2−x+zGe2+n−z (n = 3, 4)

Abstract: High-temperature solid-state reactions of the respective elements afforded the new transition metal Zintl phases Ca3CuGe3 (Sc3NiSi3 type, monoclinic C2/m – i7, Pearson code mC28), Ca6MnxAg2–x+zGe6–z (own type, monoclinic P21/m –...

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