We prove new well-posedness results for energy-critical nonlinear Schrödinger equations in modulation spaces, which are larger than the energy space. First, we remove the ε-derivative loss in L p -smoothing estimates for the linear Schrödinger equation, if p is larger than the Tomas-Stein exponent. Next, we show local well-posedness results for nonlinear Schrödinger equations in modulation spaces containing the scaling critical L 2 -based Sobolev space. The proof is carried out via bilinear refinements and adapted function spaces.