Ultrathin Layered Structure and Oxygen Vacancies Mediated Efficient Charge Separation toward High Photocatalytic Activity in BiOIO₃ Nanosheets

Abstract

Previous bismuth-based photocatalysts usually employ a strong acid solution (e.g., HNO 3 solution) to obtain an ultrathin structure toward high photocatalytic activity. In this work, the ultrathin layered BiOIO 3 nanosheets are successfully synthesized using just the glucose hydrothermal solution. The high-concentration glucose solution shows the obvious acidity after the hydrothermal process, which leads to the quick decrease in thickness of BiOIO 3 nanosheets from ∼45.58 to ∼5.74 nm. The ultrathin structure can greatly improve charge carriers' separation and transfer efficiency. The generation of reductive iodide ions brings about oxygen vacancies in the ultrathin nanosheets, then the defect energy level is formed, causing the decreased band gap and improving the visible light absorption. Compared to thick BiOIO 3 nanosheet with little oxygen vacancies, much higher carrier separation efficiency and visible light absorption are achieved in the ultrathin nanosheets with oxygen vacancies, resulting in an excellent photocatalytic performance (0.1980 min −1 for RhB degradation), which is much higher than most other bismuth-based photocatalysts. The superoxide radicals ( • O 2 − ) and holes (h + ) are the major active species responsible for high photocatalytic activity. This work affords an environmentally friendly strategy to synthesize ultrathin photocatalysts with superior photocatalytic properties.