2023
DOI: 10.1016/j.seppur.2022.122635
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Ultrasound-activated peracetic acid to degrade tetracycline hydrochloride: Efficiency and mechanism

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Cited by 38 publications
(4 citation statements)
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“…8, the photodegradation process of TC-HCl includes demethylation, deamination, deoxygenation, hydroxylation, and break removal of the piperazine ring. 53 In path 1, hydroxylation, demethylation, and deamination of TC-HCl macromolecular groups yielded P1 ( m / z = 461), P2 ( m / z = 433), P3 ( m / z = 419), and P4 ( m / z = 371). P4 ( m / z = 371), P5 ( m / z = 279) and P6 ( m / z = 210) intermediates obtained with the piperazine ring breakage, deamination and dehydroxylation.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…8, the photodegradation process of TC-HCl includes demethylation, deamination, deoxygenation, hydroxylation, and break removal of the piperazine ring. 53 In path 1, hydroxylation, demethylation, and deamination of TC-HCl macromolecular groups yielded P1 ( m / z = 461), P2 ( m / z = 433), P3 ( m / z = 419), and P4 ( m / z = 371). P4 ( m / z = 371), P5 ( m / z = 279) and P6 ( m / z = 210) intermediates obtained with the piperazine ring breakage, deamination and dehydroxylation.…”
Section: Resultsmentioning
confidence: 99%
“…8, the photodegradation process of TC-HCl includes demethylation, deamination, deoxygenation, hydroxylation, and break removal of the piperazine ring. 53 intermediates. P11 (m/z = 234) is obtained by dehydroxylation of P10, and through further demethylation can obtain P12 (m/z = 149).…”
Section: Analysis Of Degradation Pathwaysmentioning
confidence: 99%
“…Additionally, the influence of PAA concentration was further investigated, and the best CL response (Figure S8c) and degradation efficiency (Figure S6c) were obtained at 0.2 mM PAA. However, decomposition and CL emission were slightly inhibited when the concentration of PAA was increased to 0.4 mM, possibly because of the elimination effect of superfluous PAA to ROS [29]. In addition, the flow rate also had an effect on CL emission, and the optimal CL response was observed at 70 rpm (Figure S8d).…”
Section: Resultsmentioning
confidence: 99%
“…Nevertheless, PAA alone could only directly degrade certain organic contaminants with electron-rich structures (e.g., sulfur moiety, aromatic ring, and CC bond) . Up to now, a number of activation strategies have been proposed to enhance the oxidative performance of PAA, such as energy input (e.g., ultraviolet, , heat, electrochemistry, microwave, and ultrasound), metal catalysts (e.g., homogeneous and heterogeneous transition metals), carbon materials, , and anionic catalysts (e.g., phosphate, bromide, , iodine, , chloride, and nitrite), etc.…”
Section: Introductionmentioning
confidence: 99%