Ultrasonic-enhanced selective arsenic removal and sulfide conversion from iron slag

Chen, Yuefeng; Lin, Guo; Wang, Shixing; Liu, Hongliang; Fu, Likang; Xiang, Dawei; Zhu, Manying

doi:10.1016/j.jclepro.2024.141885

Cited by 2 publications

(1 citation statement)

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“…These conditions help improve mass transfer, accelerate chemical reactions, and increase the efficiency of extracting target components from a solid substrate. Ultrasound-assisted leaching has been successfully used in leaching arsenic from contaminated soils [33], gypsum [34], coal-associated rock samples [35], iron slag [36]. However, to our knowledge, ultrasound has not been used in the leaching of metals from CFD, including arsenic.…”

Section: Introductionmentioning

confidence: 99%

Ultrasound-Assisted Selective Leaching of Arsenic from Copper Smelting Flue Dust

Kenzhaliyev,

Ketegenov,

Mussapyrova

et al. 2024

Minerals

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Copper smelting flue dust (CFD) is a byproduct of pyrometallurgical copper production, containing valuable metals like lead, zinc, and copper, but also hazardous arsenic, which complicates its handling and recycling. Traditional methods for arsenic removal from CFD, such as pyrometallurgical and hydrometallurgical processes, are often inefficient or result in the loss of valuable metals. This study explores the efficacy of ultrasound-assisted leaching for selective arsenic extraction from CFD, offering a potentially more efficient and environmentally friendly alternative. We employed a combination of sodium hydroxide and sodium sulfide in an aqueous solution, enhanced by ultrasonic waves, to selectively recover arsenic into solution. The optimal leaching conditions were determined to be 0.4 M NaOH, 0.2 M Na2S, a liquid-to-solid ratio of 50 mL/g, a temperature of 80 °C, an ultrasound power of 150 W, and an ultrasound frequency of 100 kHz, under which up to 99% of arsenic was extracted within 45 min. The kinetic analysis conducted suggests that the leaching process is controlled by the chemical reactions occurring at the surface of the particles.

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