Abstract:Recently discovered phenomena of quill and non-reciprocal femtosecond laser writing in glasses and crystals are reviewed. Common beliefs that laser writing does not change when reversing beam scan or propagation direction are challenged. Ultrafast-lasers material processing has attracted considerable interest due to a wide range of applications including laser surgery, integrated optics, optical data storage, 3D micro-and nanostructuring. Three different types of material modifications can be induced with ultrafast laser irradiation in the bulk of a transparent material, silica glass in particular: an isotropic refractive index change (type 1); a form birefringence associated with self-assembled nanogratings and negative refractive index change (type 2) [1,2]; and a void (type 3). In fused silica the transition from type 1 to type 2 and finally to type 3 modification is observed with an increase of fluence.Recently, a remarkable phenomenon in ultrafast laser processing of transparent materials has been reported manifesting itself as a change in material modification by reversing the writing direction ( Fig.1) [3]. The interpretation of the phenomenon is based on anisotropic plasma trapping and heating by a tilted front of the ultrashort laser pulse. Writing direction dependence was also observed in shear stress of femtosecond laser induced lines [4]. More recently, we have experimentally demonstrated that indeed the pulse front tilt [5] can be used as a new tool material modification control and optical manipulation, e.g. for achieving calligraphicstyle laser writing, when the appearance of a "stroke" varies in relation to its direction [6].It has also been a common belief that in a homogeneous medium, the photosensitivity and corresponding light-induced material modifications do not change on the reversal of light propagation direction. Recently, we have demonstrated that when the direction of the femtosecond laser beam is reversed from +Z to -Z directions, the structures written in a lithium niobate crystal are mirror images when translating the beam along the +Y and -Y directions (Fig. 2) [7]. In contrast to glass, the directional dependence of writing in lithium niobate depends on the orientation of the crystal with respect to the direction of the beam movement and the light propagation direction. We demonstrate theoretically that interplay of the crystal anisotropy and light-induced heat flow gives rise to a new nonreciprocal nonlinear optical phenomenon, nonreciprocal photosensitivity. In the lithium niobate, the nonreciprocal photosensitivity manifests itself as a changing the sign of the light-induced current when the light propagation direction is reversed. Therefore, in a non-centrosymmetric medium, modification of the material can be different when light propagates in opposite directions. Non-reciprocity is a214_1.pdf OSA / BGPP 2010 BWB1.pdf BWB1.pdf