Ultraselective Gas Separation by Nanoporous Metal−Organic Frameworks Embedded in Gas‐Barrier Nanocellulose Films

Matsumoto, Makoto; Kitaoka, Takuya

doi:10.1002/adma.201504784

Cited by 121 publications

(59 citation statements)

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Absorption bands in the 1500–800 cm −1 spectral region are attributed to CH, OH, CO, and COC vibrations of the glucosidic ring, representing the fingerprint of the cellulose. The peak corresponding to the carboxylate groups of TOCNF at 1600 cm −1 broadens and shifts to a lower wavenumber, which could be related to the interaction of ZIF‐8 with carboxylate groups . In the spectra of CelloZIF8s and CelloZIF8‐Curs, the presence of imidazole molecule is associated with the emergence of peaks around 1580 cm −1 (CN stretch mode), bands at 1300–1500 cm −1 (entire ring stretching) and 2904 cm −1 due to the aliphatic CH stretch of the imidazole .…”

Section: Resultsmentioning

confidence: 99%

“…The TOCNF has a typical cellulose I crystal structure and is selected due to its unique properties, such as high aspect ratio (>100), negative zeta potential (≈−75 mV in water), good mechanical performance, gel formation capabilities, and 3D printability . The presence of anionic charge on TOCNF surfaces will facilitate the interaction of metal cations with TOCNFs, which serve as a substrate for direct growth of MOFs . Zeolitic imidazolate framework (ZIF‐8) and MIL‐100 (Fe) (MIL = Materials Institute of Lavoisier) have been investigated as MOF models.…”

Section: Introductionmentioning

confidence: 97%

“…Furthermore, MOFs are usually integrated with other functional materials to obtain multifunctional platforms . Flat sheets, paper, or aerogels of bacterial cellulose, carboxymethylated cellulose, and tempo oxidized cellulose nanofiber were earlier reported as substrates for in situ growing of MOFs for various applications . As compared to these techniques, 3D printing offers valuable advantages, such as high reproducibility, fabrication of complex geometries, controlled pore structures, tailored directionality, low cost, time effectiveness, and up‐scalability.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

CelloMOF: Nanocellulose Enabled 3D Printing of Metal–Organic Frameworks

Sultan

Abdelhamid

Zou

et al. 2018

Adv Funct Materials

168

126

View full text Add to dashboard Cite

3D printing is recognized as a powerful tool to develop complex geometries for a variety of materials including nanocellulose. Herein, a one-pot synthesis of 3D printable hydrogel ink containing zeolitic imidazolate frameworks (ZIF-8) anchored on anionic 2,2,6,6-tetramethylpiperidine-1-oxylradicalmediated oxidized cellulose nanofibers (TOCNF) is presented. The synthesis approach of ZIF-8@TOCNF (CelloZIF8) hybrid inks is simple, fast (≈30 min), environmentally friendly, takes place at room temperature, and allows easy encapsulation of guest molecules such as curcumin. Shear thinning properties of the hybrid hydrogel inks facilitate the 3D printing of porous scaffolds with excellent shape fidelity. The scaffolds show pH controlled curcumin release. The synthesis route offers a general approach for metal-organic frameworks (MOF) processing and is successfully applied to other types of MOFs such as MIL-100 (Fe) and other guest molecules as methylene blue.This study may open new venues for MOFs processing and its large-scale applications.

show abstract

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 97%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

CelloMOF: Nanocellulose Enabled 3D Printing of Metal–Organic Frameworks

Sultan

Abdelhamid

Zou

et al. 2018

Adv Funct Materials

168

126

View full text Add to dashboard Cite

show abstract

“…Thus, it is regarded as a suitable alternative to save the tremendous energy of distillation-based separation. Metal-organic frameworks (MOFs) [8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23], a class of promising porous materials, offer promise for gas storage and separation due to their highly versatile nature in pore structure and functionalization [24][25][26][27][28][29][30][31][32][33][34][35][36][37]. Some accomplished pore tuning strategies were used to directly increase the pore sizes within MOFs aiming at gas storage at high pressure.…”

Section: Introductionmentioning

confidence: 99%

A water-stable fcu-MOF material with exposed amino groups for the multi-functional separation of small molecules

et al. 2019

View full text Add to dashboard Cite

The energy-efficient purification of methane from C 2-hydrocarbons is of great significance for the upgrading of natural gas. So does the capture of carbon dioxide for remission of greenhouse effect. It is well established that some functional sites, such as open metals sites, Lewis basic nitrogen sites and fluorine groups, have shown significantly enhanced affinity toward more polarizable molecules. Thus, a water-stable Eu 3+-based fcu-metal-organic framework (MOF) (compound 1) with amino functional groups has been successfully constructed through a reticular chemistry approach. As a result, the activated compound 1 exhibits moderately high uptakes of C 2-hydrocarbons, but a less obvious adsorption of CH 4 at the same conditions. Among them, the adsorption capacity of C 2 H 2 is up to 143.6 cm 3 cm −3 and a relatively high selectivity of C 2 H 2 /CH 4 (107.7) is obtained at near room temperature. Moreover, compound 1 is also validated as an exceptional adsorbent for CO 2 capture, with the fairly high capacity of CO 2 (92.6 cm 3 cm −3) and CO 2 /N 2 selectivity (151.7) at ambient conditions. The excellent performance of compound 1 is mainly driven by the exposed amino functional groups within the contracted pores. Such effect thus leads to the achievement of dual-functional platform for methane purification and carbon dioxide capture. Furthermore, compound 1 features a satisfactory water stability, which is confirmed by the powder X-ray diffraction (PXRD) analysis and the retest of porosity after being soaked in water.

show abstract

“…Matsumoto et al developed a ZIF-90/nanocellulose hybrid membrane by in-situ growth of the MOF particles on the nanocellulose fiber surfaces [94]. The nanocellulose fibers were treated via a TEMPO-mediated oxidation process.…”

Section: Nanocellulose/metal Organic Framework Hybrid Membranesmentioning

confidence: 99%

A Brief Review of Nanocellulose Based Hybrid Membranes for CO2 Separation

Dai

Ottesen

Deng

et al. 2019

Fibers

View full text Add to dashboard Cite

Due to the high specific surface area, high mechanical strength and broad possibility of surface modification, nanocellulose has obtained much attention as a new class of bio-based nanomaterials with promising potential in a wide variety of applications. Recently, a considerable amount of research has been aimed to the fabrication of nanocellulose based hybrid membranes for water treatment. However, nanocellulose based hybrid gas separation membrane is still a new research area. Herein, we force on recent advancements in the fabrication methods and separation performances of nanocellulose-based hybrid membranes for CO2 separation, the transport mechanisms involved, along with the challenges in the utilization of nanocellulose in membranes. Finally, some perspectives on future R&D of nanocellulose-based membranes for CO2 separation are proposed.

show abstract

Ultraselective Gas Separation by Nanoporous Metal−Organic Frameworks Embedded in Gas‐Barrier Nanocellulose Films

Cited by 121 publications

References 37 publications

CelloMOF: Nanocellulose Enabled 3D Printing of Metal–Organic Frameworks

CelloMOF: Nanocellulose Enabled 3D Printing of Metal–Organic Frameworks

A water-stable fcu-MOF material with exposed amino groups for the multi-functional separation of small molecules

A Brief Review of Nanocellulose Based Hybrid Membranes for CO2 Separation

Contact Info

Product

Resources

About