Here, we demonstrate the radiative polarization of high-energy electron beams in collisions with ultrashort pulsed bi-chromatic laser fields. Employing a Boltzmann kinetic approach for the electron distribution allows us to simulate the beam polarization over a wide range of parameters and determine the optimum conditions for maximum radiative polarization. Those results are contrasted with a Monte-Carlo algorithm where photon emission and associated spin effects are treated fully quantum mechanically using spin-dependent photon emission rates. The latter method includes realistic focusing laser fields, which allows us to simulate a near-term experimentally feasible scenario of a 8 GeV electron beam scattering from a 1 PW laser pulse and provide a measurement that would verify the ultrafast radiative polarization in high-intensity laser pulses that we predict. Aspects of spin dependent radiation reaction are also discussed, with spin polarization leading to a measurable (5%) splitting of the energies of spin-up and spin-down electrons.One of the driving forces in the development of petawatt class laser systems [1-3] is related to novel laserplasma based accelerator concepts. Recent laser wakefield acceleration experiments have demonstrated acceleration of electrons up to 8 GeV energy in a single stage [4] and may enable future novel TeV electron-positron colliders for high-energy physics [5,6]. Spin-polarized beams are crucial for high-energy collider applications, for instance in order to suppress the standard-model background in searches for new physics beyond the standard model [7,8]. Studying the dynamics of spin-polarized electrons in a plasma wakefield is therefore important [9][10][11]. Spin forces have been suggested to be important in both astrophysical systems and high intensity laserplasma interactions [12]. With increasing interest in high intensity laser-plasma interactions, it is essential to understand lepton spin effects on the overall plasma dynamics through radiation reaction-because of the spindependence in the photon emission rates-and electronpositron pair generation [13]. There has been notable recent interest in spin polarization of leptons in highintensity laser interactions [14][15][16].It is known that initially unpolarized lepton beams radiatively polarize in storage rings due to asymmetries in the rates for synchrotron emission; the so-called Sokolov-Ternov effect [17][18][19]. As a result, their projected spins end up being predominantly anti-aligned with the magnetic field direction. For most machines this is a slow process, with a timescale of minutes or hours, scaling as T ∝ γ/χ 3 [18,19], where χ = e 2 p.F 2 .p/m 3 = γ|e|B/m 2 1 is the quantum nonlinearity parameter, with the field strength tensor F and electron mass m, charge e and four-momentum p µ with Lorentz factor γ = p 0 /m [20].We previously demonstrated that a similar spin-up electrons down electrons FIG. 1. Electrons propagating through a bi-chromatic laser pulse perform spin-flips dominantly in certain phases ϕ of the f...