Ultramicroporous Tröger’s Base Framework Membranes for pH-Neutral Aqueous Organic Redox Flow Batteries
Junmin Liu,
Wenyi Wu,
Peipei Zuo
et al.
Abstract:Processable polymers of intrinsic microporosity (PIMs) are emerging as promising candidates for next-generation ion exchange membranes (IEMs). However, especially with high ion exchange capacity (IEC), IEMs derived from PIMs suffer from severe swelling, thus, resulting in decreased selectivity. To solve this problem, we report ultramicroporous polymer framework membranes constructed with rigid Troger's Base network chains, which are fabricated via an organic sol−gel process. These membranes demonstrate excelle… Show more
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