Solar-to-chemical
energy conversion via heterogeneous photocatalysis
is one of the sustainable approaches to tackle the growing environmental
and energy challenges. Among various promising photocatalytic materials,
plasmonic-driven photocatalysts feature prominent solar-driven surface
plasmon resonance (SPR). Non-noble plasmonic metals (NNPMs)-based
photocatalysts have been identified as a unique alternative to noble
metal-based ones due to their advantages like earth-abundance, cost-effectiveness,
and large-scale application capability. This review comprehensively
summarizes the most recent advances in the synthesis, characterization,
and properties of NNPMs-based photocatalysts. After introducing the
fundamental principles of SPR, the attributes and functionalities
of NNPMs in governing surface/interfacial photocatalytic processes
are presented. Next, the utilization of NNPMs-based photocatalytic
materials for the removal of pollutants, water splitting, CO2 reduction, and organic transformations is discussed. The review
concludes with current challenges and perspectives in advancing the
NNPMs-based photocatalysts, which are timely and important to plasmon-based
photocatalysis, a truly interdisciplinary field across materials science,
chemistry, and physics.