The
fabrication of suspended gold/carbon composite nanofibers on
carbon microposts by electrospinning of a gold/polyacrylonitrile (AuNP/PAN)
blend precursor is proposed. The fibers were spun on a rotating drum
collector for a short duration and carbonized at 900 °C in an
inert atmosphere. The in situ fabrication of a monolithic carbon structure
consisting of carbon nanofibers on carbon microposts ensures good
electrical connection, thereby reducing ohomic resistive mismatch.
It was found that the conductivity can be simply tuned about an order
of magnitude, compared to virgin carbon nanofibers, by the addition
of gold nanoparticles (AuNPs). The conductivity was found to increase
with the size (5–20 nm) of the AuNPs, which engendered graphitic
microregions in the pyrolyzed nanofibers. The effect of microfabrication/nanofabrication
technique on the organization of graphitic planes in the electrospun
composite nanofibers studied experimentally and computationally and
a templating effect of AuNPs that causes enriched graphitization is
proposed.