Highest purity calcium difluoride crystals having a roughness below 1 nm over
large areas were prepared by ultra-precision machining to create technical
surfaces for optical applications. High resolution dynamic scanning force
microscopy reveals surfaces with close to atomic flatness over areas larger than
10 µm2. The residual roughness is due to a high density of pits and protrusions with a height of 0.32 nm
corresponding to an F–Ca–F triple-layer that is the smallest possible unit on stoichiometric
CaF2(111). Additionally, imperfections of the machining process may appear as protrusions of
typically 1 nm height or a high density of aligned triple-layer steps for surfaces
that were apparently slightly inclined with respect to the machining plane. A
terraced structure also appears in the vicinity of nanometre-sized defects found
for one sample. Machining may also cause a fracture in the form of branched
channels of some tens of nanometres in width and some micrometers in length.