Ultra‐low Mn(salen) supported on lignin and selective epoxidation of olefins
Li Guo,
Ting Yan,
Ran Zhang
et al.
Abstract:Precise design of highly efficient, low metal load and eco‐friendly catalysts is the key to sustainable catalysis and green chemistry. In this work, we develop an ultra‐low loading of Mn(salen) complexes covalent grafted with lignin and applied in the selective epoxidation of olefins using O2 as an oxidant. Lignin not only provides the Mn(salen) graft sites but also promotes substrate enrichment via the π‐stacking interaction between substrate and supports. In particular, high turnover frequencies (TOF) of 183… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.