Ultra-high-performance aluminum-based hybrid supercapacitors prepared for nitrogen-doped micro-mesoporous carbon sphere

Sun, Weiyi; Xing, Lingli; Zhang, Bomian; Shi, Wenchao; Ren, Jingke; Zhang, Xinyu; Xiong, Fangyu; An, Qinyou

doi:10.1016/j.jpowsour.2023.233052

Cited by 7 publications

(6 citation statements)

References 35 publications

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“…Sun et al recently employed high SSA micro-mesoporous carbon spheres as cathodes with N doping from phenol resin and melamine precursors. 111 The constructed AIC device with an aluminum anode exhibited a discharge capacity of 224 mAh g −1 . A comparison of all heteroatom-doped CIC and AIC fullcell devices with all parameters is provided in Table 5.…”

Section: Acs Applied Nano Materialsmentioning

confidence: 97%

“…The assembled AIC device exhibited a discharge capacity of 240 F g –1 at 0.1 A g –1 and retained a capacity of 254 F g –1 over 10,000 cycles. Sun et al recently employed high SSA micro-mesoporous carbon spheres as cathodes with N doping from phenol resin and melamine precursors . The constructed AIC device with an aluminum anode exhibited a discharge capacity of 224 mAh g –1 .…”

Section: Heteroatom-doping In Dual Carbon Metal Ion Capacitorsmentioning

confidence: 99%

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A Brief Review on Heteroatom-Doped Dual-Carbon Metal-Ion Hybrid Capacitors: The Role of Carbon Nanomaterials

Apparla,

Gopalakrishnan,

Sharma

2024

ACS Appl. Nano Mater.

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Numerous carbon nanomaterials, due to their affordability, safety, and tunability, are being widely investigated for energy storage applications. Dual carbon energy storage devices, from supercapacitors to batteries, are promising devices trending in recent years. This review focuses on the role of carbon nanomaterials in heteroatom-doped dual-carbon metal-ion hybrid capacitors (DC-MIC) from lithium to potassium and multivalent ions. DC-MIC is the combination of a carbon anode with a batterylike characteristic and a carbon cathode with capacitor-like characteristics, assembled in a single cell with a nonaqueous electrolyte. The research growth and issues surrounding dual carbon devices, the impact of heteroatom doping, their chargestorage mechanism, and electrode characteristics are introduced in the first section of this review. The next part deals with the reported doped carbon nanomaterials for DC-MIC from lithium to potassium and multivalent ion hybrid devices. Finally, projections for future investigations and insights are provided for doped DC-MIC devices.

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Section: Acs Applied Nano Materialsmentioning

confidence: 97%

Section: Heteroatom-doping In Dual Carbon Metal Ion Capacitorsmentioning

confidence: 99%

A Brief Review on Heteroatom-Doped Dual-Carbon Metal-Ion Hybrid Capacitors: The Role of Carbon Nanomaterials

Apparla,

Gopalakrishnan,

Sharma

2024

ACS Appl. Nano Mater.

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“…The FESEM study revealed crumpled graphene layers stacked on each other, resulting in a large SSA that facilitates electrochemical reactions. Sun et al [89] presented using a nitrogen-doped micro-mesoporous carbon sphere (NCS) as a negatrode material in aluminium-based HSCs. The NCS was produced by combining phenolic resin with melamine in a 1:1 mass ratio, followed by carbonization at 600 • C in nitrogen.…”

Section: Synthesis Of Bdc Materials For Aihscsmentioning

confidence: 99%

Biomass-Derived Carbon Materials for Advanced Metal-Ion Hybrid Supercapacitors: A Step Towards More Sustainable Energy

Shah

2024

Batteries

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Modern research has made the search for high-performance, sustainable, and efficient energy storage technologies a main focus, especially in light of the growing environmental and energy-demanding issues. This review paper focuses on the pivotal role of biomass-derived carbon (BDC) materials in the development of high-performance metal-ion hybrid supercapacitors (MIHSCs), specifically targeting sodium (Na)-, potassium (K)-, aluminium (Al)-, and zinc (Zn)-ion-based systems. Due to their widespread availability, renewable nature, and exceptional physicochemical properties, BDC materials are ideal for supercapacitor electrodes, which perfectly balance environmental sustainability and technological advancement. This paper delves into the synthesis, functionalization, and structural engineering of advanced biomass-based carbon materials, highlighting the strategies to enhance their electrochemical performance. It elaborates on the unique characteristics of these carbons, such as high specific surface area, tuneable porosity, and heteroatom doping, which are pivotal in achieving superior capacitance, energy density, and cycling stability in Na-, K-, Al-, and Zn-ion hybrid supercapacitors. Furthermore, the compatibility of BDCs with metal-ion electrolytes and their role in facilitating ion transport and charge storage mechanisms are critically analysed. Novelty arises from a comprehensive comparison of these carbon materials across metal-ion systems, unveiling the synergistic effects of BDCs’ structural attributes on the performance of each supercapacitor type. This review also casts light on the current challenges, such as scalability, cost-effectiveness, and performance consistency, offering insightful perspectives for future research. This review underscores the transformative potential of BDC materials in MIHSCs and paves the way for next-generation energy storage technologies that are both high-performing and ecologically friendly. It calls for continued innovation and interdisciplinary collaboration to explore these sustainable materials, thereby contributing to advancing green energy technologies.

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“…Sun et al [71] constructed an aluminum-based energy storage device using a hybrid capacitor-battery mechanism. The device includes an aluminum foil negatrode, a high-specific-area nitrogen-doped micro-mesoporous carbon sphere (NCS) positrode, an imidazole electrolyte, a glass microfiber filter (GF/A) separator, and a molybdenum foil current collector.…”

Section: Metallic Aluminum Negatrodementioning

confidence: 99%

“…Sun et al [71] . constructed an aluminum‐based energy storage device using a hybrid capacitor‐battery mechanism.…”

Section: Metallic Negatrode‐based Mnscsmentioning

confidence: 99%

Metal Negatrode Supercapatteries: Advancements, Challenges, and Future Perspectives for High‐Performance Energy Storage

Johan,

Ali,

Shuaibu

et al. 2023

The Chemical Record

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Metal negatrode supercapattery (MNSC) is an emerging technology that combines the high energy storage capabilities of batteries with the high‐power delivery of supercapacitors, thereby offering promising solutions for various applications, such as energy storage systems, electric vehicles, and portable electronics. This review article presents a comprehensive analysis of the potential of MNSCs as a prospective energy storage technology. MNSCs utilize a specific configuration in which the negatrode consists of a metal or metal‐rich electrode, such as sodium, aluminum, potassium, or zinc, whereas the positrode functions as a supercapacitor electrode. The utilization of negatrodes with low electrochemical potential and high electrical conductivity is crucial for achieving high specific energy in energy storage devices, despite facing numerous challenges. The present study discusses the design and fabrication aspects of MNSCs, including the selection of appropriate metal negatrodes, electrolytes, and positrodes, alongside the fundamental operational mechanisms. Additionally, this review explores the challenges encountered in MNSCs and proposes solutions to enhance their performance, such as addressing dendrite formation and instability of metal electrodes.

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Ultra-high-performance aluminum-based hybrid supercapacitors prepared for nitrogen-doped micro-mesoporous carbon sphere

Cited by 7 publications

References 35 publications

A Brief Review on Heteroatom-Doped Dual-Carbon Metal-Ion Hybrid Capacitors: The Role of Carbon Nanomaterials

A Brief Review on Heteroatom-Doped Dual-Carbon Metal-Ion Hybrid Capacitors: The Role of Carbon Nanomaterials

Biomass-Derived Carbon Materials for Advanced Metal-Ion Hybrid Supercapacitors: A Step Towards More Sustainable Energy

Metal Negatrode Supercapatteries: Advancements, Challenges, and Future Perspectives for High‐Performance Energy Storage

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