Ueber Nitrosotoluidine

Mehne, Paul R.

doi:10.1002/cber.188802101132

Cited by 2 publications

(1 citation statement)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Many derivatives of 1,4-dinitrosobenzene have been prepared and shown to share the behavior of the parent compound, including (1) the formation of insoluble polymers incorporating trans -azodioxy groups and (2) facile thermal depolymerization to regenerate the monomeric form. − An exception is 2,5-di- tert -butyl-1,4-dinitrosobenzene, which does not polymerize because of important steric hindrance created by the presence of two ortho-tert -butyl groups . 1,3-Dinitrosobenzene ( 20 ), first reported in 1905 by Alway and Gortner, polymerizes spontaneously at room temperature and yields poly( trans -1,3-phenyleneazo- N , N ′-dioxide) ( 21 ) (eq ).…”

Section: Aromatic Dinitroso and Polynitroso Compoundsmentioning

confidence: 99%

Dimerization of Aromatic C-Nitroso Compounds

2016

View full text Add to dashboard Cite

Aromatic C-nitroso compounds (Ar-N═O) and related species have a rich chemical history, and they continue to interest researchers in many fields. Among the most distinctive and puzzling properties of these compounds is their ability to dimerize reversibly to form azodioxy compounds. The present review subjects this intriguing phenomenon to comprehensive analysis. All aspects of the subject are examined in detail, including the structures of monomeric and dimeric forms, the mechanism of dimerization, features that favor or disfavor dimerization, thermodynamic and kinetic factors, dimerization under specific conditions (including in solution, in the solid state, and on surfaces), and the special associative behavior of dinitroso and polynitroso compounds. By summarizing the current state of knowledge, the review promises to spur further advances in the evergreen field of C-nitroso chemistry, including the discovery of new ways to exploit the reversible dimerization of nitrosoarenes.

show abstract

Section: Aromatic Dinitroso and Polynitroso Compoundsmentioning

confidence: 99%

Dimerization of Aromatic C-Nitroso Compounds

2016

View full text Add to dashboard Cite

show abstract

Dinitroso and polynitroso compounds

Gowenlock

Richter‐Addo

2005

Chem. Soc. Rev.

View full text Add to dashboard Cite

The growing interest in the chemistry of C-nitroso compounds (RN=O; R = alkyl or aryl group) is due in part to the recognition of their participation in various metabolic processes of nitrogen-containing compounds. C-Nitroso compounds have a rich organic chemistry in their own right, displaying interesting intra- and intermolecular dimerization processes and addition reactions with unsaturated compounds. In addition, they have a fascinating coordination chemistry. While most of the attention has been directed towards C-nitroso compounds containing a single -NO moiety, there is an emerging area of research dealing with dinitroso and polynitroso compounds. In this critical review, we present and discuss the synthetic routes and properties of these relatively unexplored dinitroso and polynitroso compounds, and suggest areas of further development involving these compounds. (126 references.).

show abstract

Ueber Nitrosotoluidine

Cited by 2 publications

References 0 publications

Dimerization of Aromatic C-Nitroso Compounds

Dimerization of Aromatic C-Nitroso Compounds

Dinitroso and polynitroso compounds

Contact Info

Product

Resources

About