Ueber alkylschwefligsaure Salze

Rosenheim, Arthur; Liebknecht, Otto

doi:10.1002/cber.18980310186

Cited by 18 publications

(2 citation statements)

References 5 publications

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“…The only exception to this rule reported (75) is that the alkaline hydrolysis of the cyclic sulfite of cfs-1,2-cyclohexanediol yields almost exclusively irans-l,2-diol, contrary to the reaction in acid. In the earliest reported experiments on alkaline hydrolysis (2,199) alkali salts of sulfonic acids were found among the products. Baggesgaard-Rasmussen (9), reinvestigating this point, concluded that hydrolysis is normal in excess base where the reaction is fast and complete, but under conditions where unreacted dialkyl sulfite and inorganic sulfite can interact slowly, a small percentage of alkane sulfonate may be formed, analogous to the reactions observed by Strecker and Mayer (vide section IIIF, alkylation).…”

Section: E Hydrolysismentioning

confidence: 99%

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Organic Sulfites.

Woerden¹

1963

Chem. Rev.

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Section: E Hydrolysismentioning

confidence: 99%

“…chlorides (38,87) and metal salts (199,237,240) of the two respective classes. As sulfonic esters and ionic sulfonates are derivable from inorganic metal sulfites, these compounds were originally denoted as "sulfurous" in the German literature.…”

mentioning

confidence: 99%

Organic Sulfites.

Woerden¹

1963

Chem. Rev.

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Ueber Alkalithiosulfate des Kupfers

Rosenheim

Steinhäuser

1898

Ber. Dtsch. Chem. Ges.

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Die Darstellung von Alkylsulfinsäuren

Rosenheim

Singer

1904

Ber. Dtsch. Chem. Ges.

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wandelt. Die Destillation dvsselben , sowie die Verarbeitung des Destillates erfolgte in analoger Weise, wie es oben bei der Darstellung von Veratrol nngegeben nurtle. Da bei den geringen Mengen eine vollige Reinigung des gebildeten Veratru1ris6oreesters durch fractiouirte Destillation ausgeschloseen war, wurde die Fraction von 285-293 0 durch zweistundiges Erhitzeii [nit alkoholischer Kalilnuge ziir Saure verseift. Dabei resultirte in einer Ausbeute von ca. 30 pCt. der Theorie ein Product, d:ts iri seincrn Schmp. 179--180° und seinen Eigenschaften mit der Verntrums5nre iibereinstirnrnte. 0.1218 g Sbst. (irn Vacuum getrocknet): 0.2642 g COz, 0.0592 g H20. CsHtoOi. Rer. G z-)9.31, H 5.49. Gef. )) 59.16, 5.40. Unterwirft man das Hleisnlz des I t e a o r c i n m o n o m e t h y l 5 t h e r e der troeknen Destillation, YO enthalt das Destiilat geringe Mengen ') Diese Berichte 1 3 , 23ti5 [L880]. 3, Ann. cle 1'Cnivers. L~Q I I , nouv. sQr. 3, Diese Berichte 31, 405 [1898]. Heft 6, 1.zie tisher jedocli derartigc \'erotiche nicht bcschnieben liahm, plauben wir uuwre Xrgebnissc~ knrz mittbcilen ZII diirfen.

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Ueber alkylschwefligsaure Salze

Cited by 18 publications

References 5 publications

Organic Sulfites.

Organic Sulfites.

Ueber Alkalithiosulfate des Kupfers

Die Darstellung von Alkylsulfinsäuren

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