Über eine neue Reaktion des Chlordioxyds. Die Bildung einer Verbindung der Formel ClO₂F

Abstract

1. Aus gasförmigem Chlordioxyd und Fluor läßt sich unter ge‐eigneten Bedingungen, z. B. Chlordioxyd‐Druckenivon etwa 25 mm oder darunter, Fluordrucken von etwa 50 mm und Zusatz mehrerer hundert Millimeter inerten Gases bei einem Gesamtdruck von 1 Atm. und Temperaturen um 0°C, eine Verbindung von der Zusammensetzung ClO2F darstellen.

Reactions of ClF3 with Main Group and Transition Metal Oxides: Access to Dioxychloronium(V) Fluoridometallates and Oxidofluoridometallates

“…Chlorosyl fluoride, ClOF, has a short lifetime and disproportionates into ClF and ClO 2 F [1–4] . The latter, called chlorine dioxide fluoride or chloryl fluoride, is one of the known stable oxyfluorides of chlorine [5–8] . The other ones are chlorine oxide trifluoride ClOF 3 , perchloryl fluoride ClO 3 F, and chlorine dioxide trifluoride ClO 2 F 3 [9–14] .…”

“…ClO 2 F can be synthesized by different methods, the most important ones being the fluorination of ClO 2 (Equation (1)) or of chlorates, A [ClO 3 ] ( A =Na, K) (Equation (2) and Equation ) [5,8,16–19] …”

“…Chlorosyl fluoride, ClOF, has a short lifetime and disproportionates into ClF and ClO 2 F. [1][2][3][4] The latter, called chlorine dioxide fluoride or chloryl fluoride, is one of the known stable oxyfluorides of chlorine. [5][6][7][8] The other ones are chlorine oxide trifluoride ClOF 3 , perchloryl fluoride ClO 3 F, and chlorine dioxide trifluoride ClO 2 F 3 . [9][10][11][12][13][14] Perchloryl hypofluorite, ClO 4 F, does not possess a ClÀ F bond, as indicated by the name, and is thus different from the oxyfluorides.…”

Photochemistry with Chlorine Trifluoride: Syntheses and Characterization of Difluorooxychloronium(V) Hexafluorido(non)metallates(V), [ClOF2][MF6] (M=V, Nb, Ta, Ru, Os, Ir, P, Sb)

“…Chlorine oxide trifluoride, ClOF 3 , [1–3] is one of the currently known four stable chlorine oxyfluorides with the other three being ClO 2 F, ClO 3 F and ClO 2 F 3 [4–9] . Chlorosyl fluoride, ClOF, is unstable towards disproportionation into ClF and ClO 2 F, and is formed as an intermediate during the hydrolysis of ClF 3 [10–14] .…”

Research and Development of New and Improved Oxidizers for Use in Solid Propellants. Part 1

“…Schmitz and Shumacher (44) showed that the controlled reaction of fluorine and chlorine dioxide results in the formation of a compound FCIO z with a covalently bonded fluorine atom. A similar reaction was expected to occur with tetrafluorohydrazine.…”