Über Dioxanate der Halide zweiwertiger Metalle V. Mitteilung über Molekülverbindungen des Dioxans

Rheinboldt, Heinrich; Luyken, Alfred; Schmittmann, Herbert

doi:10.1002/prac.19371490102

Cited by 26 publications

(10 citation statements)

References 11 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…For understanding this exceptional behaviour, the tendency of Cd12 to form solvate complexes with organic Lewis bases must be taken into consideration. For example, a stable complex Cd12 -C4H802 is obtained by crystallisation from 1,Cdioxane whilst anhydrous Cd12 crystallizes from water [16]. A similar, but weaker tendency to solvate complex formation is displayed from the strong curvature of the T, = f(xEl) curves obtained with ZnC12 ( Figs.…”

Section: Discussionmentioning

confidence: 72%

The Influence of Dissolved Electrolytes on the Miscibility of Binary Liquid Systems with Closed Miscibility Gaps

Erol

Koçak

Richter

et al. 1987

Ber Bunsenges Phys Chem

View full text Add to dashboard Cite

Electrolytes J Liquids J Solutions J ThermodynamicsThe dependence of the upper and lower critical solution temperatures T, of the systems (1) oxolane + water, and (2) 2-butoxyethanol + water on the mole fraction xEl of dissolved 1-1,2-1, and 3-1 electrolytes has been investigated. The material stability of the homogeneous state of both systems is extremely sensitive to small electrolyte concentrations so that the observed shift of T, may be interpreted as the result of a perturbation of the mutual solvation of both non-electrolytes by ion solvation. Cations destabilize homogeneity in the order Me+ < Me2+ Br-> I-> NO, > C 1 0~ is established, determines whether the closed miscibility gap expands, shrinks, or is shifted to higher temperatures with increasing xEl. The importance of the anions is evident from a comparison of MgClz and Mg(CIO,),, for which the lower critical solution temperatures of oxolane + water at xEl = 0.003 differ by about 70 K.

show abstract

Section: Discussionmentioning

confidence: 72%

The Influence of Dissolved Electrolytes on the Miscibility of Binary Liquid Systems with Closed Miscibility Gaps

Erol

Koçak

Richter

et al. 1987

Ber Bunsenges Phys Chem

View full text Add to dashboard Cite

show abstract

“…Les r6-sultats de l'analyse chimique correspondaient ~t deux formules diff6rentes, soit HgBr2.2C4H802 pour le premier travail (Brand & Tfirck, 1936) et HgBr2. C4HsOz pour les deux autres (Rheinboldt et al, 1937;Crenshaw et al, 1938).…”

Section: Partie Exp6rimentaleunclassified

Structure cristalline d'un composé d'addition du bromure mercurique avec le dioxanne-1,4: HgBr2.2C4H8O2

Frey¹,

Monier²

1971

Acta Crystallogr Sect B

View full text Add to dashboard Cite

The crystal structure of a solvate of mercuric bromide with 1,4-dioxane, HgBr2.2C4HsO2 was determined from the 357 integrated intensities of the hki (i= 0, 1, 4, 5) and hjl (]= 0, 1, 2) levels registered with a precession camera. The final R was 0.079. The Hg-Br bond is 2.43 A and the dioxane ring has a chair conformation. The coordination of the mercury atoms is octahedral. The structure may be described as a stacking of layers perpendicular to e and made of HgBr2 and c4nso2 molecules bound together by Hg... O bond, length: 2.83/~. The crystal cohesion otherwise consists of van der Waals contacts between HgBr2 and C4H802 molecules of two neighbouring layers.

show abstract

“…Compounds have been reported with diethyl ether (51), and 1 , Jj-dioxane (52 ). Two recent papers have been concerned with some novel complexes.…”

mentioning

confidence: 99%

Some reactions of tin (II) chloride in nonaqueous solution

Morrison

Haendler

1967

Journal of Inorganic and Nuclear Chemistry

View full text Add to dashboard Cite

Über Dioxanate der Halide zweiwertiger Metalle V. Mitteilung über Molekülverbindungen des Dioxans

Cited by 26 publications

References 11 publications

The Influence of Dissolved Electrolytes on the Miscibility of Binary Liquid Systems with Closed Miscibility Gaps

The Influence of Dissolved Electrolytes on the Miscibility of Binary Liquid Systems with Closed Miscibility Gaps

Structure cristalline d'un composé d'addition du bromure mercurique avec le dioxanne-1,4: HgBr2.2C4H8O2

Some reactions of tin (II) chloride in nonaqueous solution

Contact Info

Product

Resources

About