1966
DOI: 10.1002/macp.1966.020900101
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Über den einfluß von reglern auf die polymerisation des trioxans

Abstract: ZUSAMMENFASSUNG:Die Untersuchung der Regelung der Trioxanpolymerisation durch verschiedene Ketteniibertrager fiihrte zu dem Ergebnis, dal3 wahrend der Polymerisation als Nebenreaktion eine Hydridwanderung stattfindet. Analytische Untersuchungen erharteten diesen Befund. Die intramolekulare Hydridwanderung liefert Methylkationen, die ihrerseits die Polymerisation oder eine Transacetalisierung auslosen. Hydridwanderung und Transacetylisierung sind fiir die kationische Polymerisation von Trioxan und Formaldehyd c… Show more

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Cited by 41 publications
(2 citation statements)
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“…However, POM-based block copolymers might be an interesting alternative to the random copolymerization approach to improve processing and to modify the property profile of POM. Some attempts to tailor the properties of POM by introducing functional groups mainly relied on three strategies: (i) conversion of the two hydroxyl end groups with suitable reagents, , (ii) integration of functional groups into the polymer backbone by transfer reactions during the polymerization, ,,, or (iii) copolymerization of trioxane with functional comonomers …”
Section: Introductionmentioning
confidence: 99%
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“…However, POM-based block copolymers might be an interesting alternative to the random copolymerization approach to improve processing and to modify the property profile of POM. Some attempts to tailor the properties of POM by introducing functional groups mainly relied on three strategies: (i) conversion of the two hydroxyl end groups with suitable reagents, , (ii) integration of functional groups into the polymer backbone by transfer reactions during the polymerization, ,,, or (iii) copolymerization of trioxane with functional comonomers …”
Section: Introductionmentioning
confidence: 99%
“…However, POM-based block copolymers might be an interesting alternative to the random copolymerization approach to improve processing and to modify the property profile of POM. Some attempts to tailor the properties of POM by introducing functional groups mainly relied on three strategies: (i) conversion of the two hydroxyl end groups with suitable reagents, 12,13 (ii) integration of functional groups into the polymer backbone by transfer reactions during the polymerization, 12,14,15,9 or (iii) copolymerization of trioxane with functional comonomers. 16 In contrast, hyperbranched poly(glycerol) (hbPG), obtained by cationic 17,18 or anionic 19,20 ring-opening multibranching polymerization (ROMBP) of glycidol, offers tremendous possibilities for further functionalization due to its polyol structure.…”
Section: ■ Introductionmentioning
confidence: 99%