Über Antimon-haltige Heterocyclen—IV. Schwingungsspektren von phenylierten Oxadithia- und Trithiastibocanen, -bismocanen, -stannocanen und -plumbocanen
“…Most of the publications are restricted only on synthesis and characterization of tin(IV) and organotin(IV) derivatives with sulphur ligands like dithiolates [6,7] and dialkyldithiocarbamates [8][9][10][11][12][13][14][15][16][17][18][19]. A large number of diorganotin(IV) dialkyldithiocarbamate derivatives have been known including X-ray crystal structures of [Ph(Bu)Sn(S 2 CNEt 2 )Cl] [11], [R 2 Sn(S 2 CNMe 2 ) 2 ] [ etc.…”
“…Most of the publications are restricted only on synthesis and characterization of tin(IV) and organotin(IV) derivatives with sulphur ligands like dithiolates [6,7] and dialkyldithiocarbamates [8][9][10][11][12][13][14][15][16][17][18][19]. A large number of diorganotin(IV) dialkyldithiocarbamate derivatives have been known including X-ray crystal structures of [Ph(Bu)Sn(S 2 CNEt 2 )Cl] [11], [R 2 Sn(S 2 CNMe 2 ) 2 ] [ etc.…”
“…A systematic investigation of stannocanes by Raman and IR spectroscopy was commenced in 1985 by M. Dräger and coworkers [50,53]. As a rule the spectra of these compounds are divided into two regions.…”
Results on the synthesis of stannocanes -eight-membered heterocycles with the general formula D(CH 2 CH 2 Z) 2 SnXY -are reviewed and analyzed. The chemical behavior of the compounds is examined, and the nature of the transannular bond is studied.
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