Two-step percolation in aggregating systems

Abstract

The two-step percolation behavior in aggregating systems was studied both experimentally and by means of Monte Carlo (MC) simulations. In experimental studies, the electrical conductivity, σ, of colloidal suspension of multiwalled carbon nanotubes (CNTs) in decane was measured. The suspension was submitted to mechanical de-liquoring in a planar filtration-compression conductometric cell. During de-liquoring, the distance between the measuring electrodes continuously decreased and the CNT volume fraction ϕ continuously increased (from 10 −3 up to ≈ 0.3% v/v). The two percolation thresholds at ϕ 1 10 −3 and ϕ 2 ≈ 10 −2 can reflect the interpenetration of loose CNT aggregates and percolation across the compact conducting aggregates, respectively. The MC computational model accounted for the core-shell structure of conducting particles or their aggregates, the tendency of a particle for aggregation, the formation of solvation shells, and the elongated geometry of the conductometric cell. The MC studies revealed two smoothed percolation transitions in σ(ϕ) dependencies that correspond to the percolation through the shells and cores, respectively. The data demonstrated a noticeable impact of particle aggregation on anisotropy in electrical conductivity σ(ϕ) measured along different directions in the conductometric cell.

Effects of Dispersed Carbon Nanotubes and Emerging Supramolecular Structures on Phase Transitions in Liquid Crystals: Physico-Chemical Aspects

“…A similar two-step percolation behavior was observed for aggregating suspension of CNTs in isotropic liquid (decane) [135]. A planar filtration-compression conductometric cell was used for mechanical de-liquoring of the suspension.…”

Enhanced electromagnetic interference shielding effectiveness of polypropylene/hybrid metallic fillers composite materials by coalescence-driven guided electrical percolation

“…that the concentration of large carbon black aggregates has a stronger influence on the percolation threshold than the concentration of small aggregates [91]. In another study [92], N.…”