Two-stage pressure-induced Yb valence change in the hexagonal Laves phase
YbAg2
: Investigation by time differential perturbed angular
γ−γ
correlation spectroscopy method and density functional calculations
Abstract:We have studied the C14 hexagonal Laves phase of YbAg2 at normal conditions and under external pressure up to 19 GPa by the time-differential perturbed angular γ − γ correlation spectroscopy (TDPAC) using 111 Cd probe nuclei. Under pressure the valence of Yb undergoes a two stage transition from 2.8 to 3. The two stage scenario is characterized by two distinct quadrupole frequencies of 111 Cd probes in silver sublattice, monotonically increasing with pressure and saturating at 8 and 16 GPa. Our experimental da… Show more
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