Two polyoxovanadoborates with over 100 nuclei assembled from a {V14Co12B72} cluster

Two High-Nuclear Wheel-Hub-Shaped Transition-Metal-Doped Polyoxovanadates

“…In 2020, Lan et al discovered the giant hollow opening dodecahedral polyoxomolybdate cage {Mo 240 } and demonstrated an exceptionally high proton conductivity . In 2022, a giant {Mo 126 W 30 } POM cage templated by π-conjugated planar ligands and stabilized by multiple π–π interactions was reported by Fang et al Other types of high-nuclear POM clusters, such as fullerene-like inorganic {V 30 Nb 12 } clusters, protein-sized windmill-like {Nb 288 } clusters, and multilayer sandwich-type polyoxovanadoborate {V 14 Co 12 B 72 }, have been successively reported, opening avenues for further research and exploration of the unique properties and applications of these giant clusters.…”