“…Continuous Stokes frequency shift with spectral broadening of femtosecond pulses under the condition of SRSS, in vibrational transitions, was experimentally observed in different media [14], when initial laser pulse duration τ o was below 100 fs. In [13,15] it was shown theoretically that under the condition of SRSS the continuous spectral broadening to Stokes direction occurred when the two-photon Rabi frequency Ω (2) , that corresponded to this stimulated Raman process, was less π/τ o . But for pulses with more intensity, when the two-photon Rabi frequency was more π/τ o (especially ∼ 2π/τ o ), the superbroadening to both anti-Stokes and Stokes direction, and the generation of spectral supercontinuum occurred [13,15].…”