Abstract:The judicious selection of suitable ligands is vitally important in the construction of novel metal–organic frameworks (MOFs) with fascinating structures and interesting properties. Recently, imidazole‐containing multidentate ligands have received much attention. Two new CdII coordination frameworks, namely, poly[tris{μ‐1,4‐bis[(1H‐imidazol‐1‐yl)methyl]benzene‐κ2N3:N3′}tetrakis(nitrato‐κ2O,O′)dicadmium], [Cd2(NO3)4(C14H14N4)3]n, (I), and poly[[bis{μ3‐1,3,5‐tris[(1H‐imidazol‐1‐yl)methyl]benzene‐κ3N3:N3′:N3′′}ca… Show more
C36H36N12NiSiF6, trigonal,
P
3
‾
$P‾{3}$
(no. 147), a = 9.5965(3) Å, c = 11.8821(8) Å, V = 947.65(9) Å3, Z = 1, R
gt
(F) = 0.0437, wR
ref
(F
2) = 0.1076, T = 223 K.
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