Abstract:Two proton-conductive molecular hybrids were constructed by introducing protonated water clusters, alkaline-earth metal ions and [PMo 12 O 40 ] 3-anions in the gallery of H-bonding networks based on isonicotinic acid N-oxide. Single-crystal X-ray diffraction analyses at 293 K revealed that two complexes crystallized in the orthorhombic space group Pnnm, exhibited very close unit cell parameters, and presented similar three-dimensional hydrogen-bonded networks with large one-dimensional (1D) channels. Interesti… Show more
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