Two Forms of Bromo(cycloheptatrienylidene)bis(triphenylphosphine)platinum(II)

Klosin, Jerzy; Jones, W. M.; Abboud, Khalil A.

doi:10.1107/s010827019501016x

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Hydrogen Atoms In C+−h Fragments1

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“…An extrapolation from the structural features of the N-substituted cations and their reactions discussed above leads to the conclusion that the C−H···X contacts in tropylium ions can also be interpreted as initial phases of the deprotonation (eq 6e). The crystal structures of several iron and platinum complexes of the carbene 157 are known. They are characterized by a σ-bond-like coordination of 157 via the carbene lone pair to the metal center.…”

Section: Hydrogen Atoms In C+−h Fragmentsmentioning

confidence: 99%