Two-dimensional rare-earth-metal coordination polymers based on biphenyl-3,3′,5,5′-tetracarboxylic acid displaying luminescence

Abstract

Two coordination polymers were rationally designed and successfully constructed using the rigid multicarboxylic acid ligand biphenyl-3,3′,5,5′-tetracarboxylic acid (H4BPTC) and rare earth metal ions (Eu3+ and Ho3+) under solvothermal conditions. The compounds are poly[[tetra-μ2-acetato-bis(μ6-biphenyl-3,3′,5,5′-tetracarboxylato)tetrakis(dimethylacetamide)tetraeuropium(III)] dimethylacetamide disolvate dihydrate], {[Eu4(C16H6O8)2(C2H3O2)4(C4H9NO)4]·2C4H9NO·2H2O} n , and poly[[tetra-μ2-acetato-bis(μ6-biphenyl-3,3′,5,5′-tetracarboxylato)tetrakis(dimethylacetamide)tetraholmium(III)] pentahydrate], {[Ho4(C16H6O8)2(C2H3O2)4(C4H9NO)4]·5H2O} n , Single-crystal X-ray diffraction analysis reveals that both polymers possess a two-dimensional structure and they also display good thermal stability up to ca 280 °C and photoluminescence with an orange–red light emission.