From nanotechnology-based thermal insulation materials nano-ceramic thermal insulation coatings are generally considered to be the most critical because of contradictory technical data that could be founded in special literature. Complete agreement had not been already found about the mechanism how does their insulating effect take. In the Laboratory of Building Materials and Building Physics at Széchenyi István University (GyĘr, Hungary) several thermodynamic tests were made in order to find out thermodynamic process inside this material. Several building structures with different order of layers were tested with heat flow meter. Results showed that convective heat transfer coefficient cannot be taken account in usual way using this material as thermal insulation.