2019
DOI: 10.1007/s12039-019-1634-5
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Two cobalt metal-organic frameworks constructed from mixed ligands and their magnetic properties

Abstract: The reaction of the polycarboxylic acid ligand tri(2-carboxyethyl)-isocyanurate (H 3 L 1), polyazo bridged ligand 1H-3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (L 2), CoCl 2 • 6H 2 O, and different organic solvents lead to the formation of two novel coordination complexes: [Co 3 (L 1) 2 (L 2) 2 (H 2 O) 4 ] n (1), [Co 3 (L 1) 2 (L 2) 2 (H 2 O) 2 ] n • 2nH 2 O (2). Two complexes were prepared under solvothermal conditions and characterized by the single-crystal X-ray diffraction, thermal analysis, element analys… Show more

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“…These complexes displayed antiferromagnetic interactions between the adjacent Co( ii ) centers. 36 Shao et al exploited a 2D Co( ii ) single-ion magnet, which exhibited slow magnetic relaxation under external fields. 37 Legendre et al developed a 3D paramagnetic Co( ii ) complex with the tunable bis(benzoxazol-2-yl)methanide ligand.…”
Section: Introductionmentioning
confidence: 99%
“…These complexes displayed antiferromagnetic interactions between the adjacent Co( ii ) centers. 36 Shao et al exploited a 2D Co( ii ) single-ion magnet, which exhibited slow magnetic relaxation under external fields. 37 Legendre et al developed a 3D paramagnetic Co( ii ) complex with the tunable bis(benzoxazol-2-yl)methanide ligand.…”
Section: Introductionmentioning
confidence: 99%