“…In recent decades, substantial theoretical and experimental endeavors have been focused on the chemistry of metal–organic frameworks (MOF) due to their captivating structural multiformities and excellent properties. − And, metal–organic frameworks based on lanthanide-transition (4f–3d) ions exhibit extraordinary physical as well as chemical properties, particularly in magnetism and photoluminescence. − As a result, a large amount of MOFs based on 4f–3d ions have been further explored, for instance, [Ln–Cu], [Ln–Cr], [Ln–Co], [Ln–Ni], and [Ln–Mn]. ,− In comparison with the well-developed cluster chemistry of metal–organic frameworks based on 4f–3d ions, the chemistry of MOFs based on 4f–3p ions has not been fully explored so far. Aluminum is the most adequate metal in the earth’s crust and is extensively employed in printing fabric, water treatment, catalysis, and optics. − It is reported that aluminum also possesses the ability of high luminescence efficiency, making it a suitable material for plasma antennas .…”