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2024
DOI: 10.1039/d3dt04325h
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Twinned versus linked organometallics - bimetallic “half-baguette” pentalenide complexes of Rh(i)

Hugh J. Sanderson,
Gabriele Kociok-Köhn,
Claire L. McMullin
et al.

Abstract: The application of Mg[Ph4Pn] and Li·K[Ph4Pn] in transmetalation reactions to a range of Rh(I) precursors led to the formation of “half-baguette” anti-[RhI(L)n]2[µ:η5:η5Ph4Pn] (L = 1,5-cyclooctadiene, norbornadiene, ethylene; n = 1,...

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