We investigate the electron spin states in the bilayer quantum Hall system at total Landau level filling factor ν = 2 exploiting current-pumped and resistively detected NMR. The measured Knight shift, KS, of 75 As nuclei reveals continuous variation of the out-of-plane electronic spin polarization between nearly full and zero as a function of density imbalance. Nuclear spin relaxation measurements indicate a concurrent development of an in-plane spin component. These results provide direct information on the spin configuration in this system and comprise strong evidence for the spin canting suggested by previous experiments.Bilayer quantum Hall (QH) systems have found rich electronic phases that emerge as a consequence of the interplay between different degrees of freedom. In particular, at total Landau level filling factor ν = 2, where two of the four lowest Landau levels split by the Zeeman and interlayer tunnel couplings are occupied, the competing spin and layer degrees of freedom lead to rich magnetic phases. When the interlayer coupling is weak, the system behaves like two independent single-layer ν = 1 systems, resulting in a ferromagnetic (F) ground state with spins in each layer aligned parallel to the magnetic field by intralayer interactions and the weak Zeeman coupling. When the tunneling is strong, on the other hand, the interlayer antiferromagnetic coupling leads to a spin-singlet (SS) ground state resembling the single-layer ν = 2 state. Inelastic light scattering [1,2] has shown a mode softening indicating the existence of another state between these two states. Theory [3,4,5,6,7,8] suggested a canted antiferromagnetic (CAF) state, where spins in the two layers have antiparallel in-plane components and parallel out-of-plane components. Transport [9,10,11] and capacitance [12] measurements have also shown a phase transition. Recently, a nuclear spin relaxation measurement [13] has revealed a gapless spin excitation mode (Goldstone mode) indicative of the in-plane antiferromagnetic order [4,5]. Although these experiments are consistent with the CAF state, direct information on the spin configuration, such as the spin polarization P z , has not been reported.Nuclear magnetic resonance (NMR) is a powerful probe for P z because the hyperfine interaction between electron and nuclear spins shifts the nuclear resonant frequency by the Knight shift K S , which is proportional to P z . In two-dimensional electron systems (2DESs), a weak signal resulting from a small number of nuclei in contact with the 2DES restricts standard NMR measurements to multiple-quantum-well systems [14,15,16,17]. Recently, a K S measurement on a single-layer system has been achieved [18], where the NMR signal from nuclei in a quantum well (QW) is resistively detected. However, the method cannot be used to measure K S in a welldeveloped QH state, where the longitudinal resistance R xx is vanishingly small regardless of the nuclear spin polarization.In this Letter, we report the measurement of K S in the bilayer ν = 2 QH state usin...