It is challenging to hydrothermally
synthesize solution-processable
MoS2, as the strong van der Waals force between MoS2 nanosheets induces self-assembly of agglomerates. Here, we
introduce poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)
(PEDOT:PSS) into the precursor to impede aggregate formation in the
hydrothermal process. A hybrid MoS2/PEDOT:PSS (MP) hydrogel
is formed due to the electrostatic interactions between the negatively
charged MoS2 and positively charged PEDOT chains. This
hydrogel can be easily dispersed in water for subsequent solution
processing such as vacuum filtration to form free-standing flexible
films or extrusion 3D printing to create novel patterns. The MP film
with a fracture strength of 18.59 MPa displays excellent electrochemical
performance in both aqueous Na2SO4 electrolyte
(474 mF cm–2) and solid-state PVA–H3PO4 electrolyte (360 mF cm–2). Flexibility
and robustness can be evidenced by high capacitance retention rates
of 94 and 89% after being repeatedly bent to 180° for 5000 cycles
in aqueous and solid-state electrolytes, respectively.