Tuning the CO2 hydrogenation activity and selectivity of TiO2 nanorods supported Rh catalyst via secondary‐metals addition
Jinyan Zhang,
Yan Shao,
Feng Zeng
et al.
Abstract:Secondary‐metals promotion is key to tune the CO2 hydrogenation performance of Rh‐based catalyst. We describe the addition of Cu or Co in TiO2 nanorods supported Rh catalyst (viz., RhMx/TiO2), showing significant impact on the CO2 hydrogenation activity and productivity. Cu addition can promote the partial hydrogenation to alcohols (methanol and ethanol), whereas Co led to the deep hydrogenation to alkanes (CH4, C2H6). Comparative time‐resolved in situ DRIFTS studies with H2/D2 isotopic exchange further reveal… Show more
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