Tuning the reactivity of Al–Ni by fine coating of halogen-containing energetic composites

Stabilization of AlH3 Crystals by the Coating of Hydrophobic PFPE and Resulted Reactivity with Ammonium Perchlorate

“…The results show that the decomposition step of the raw AlH 3 closely follows the 3D nucleation and nucleus growth model (A3). Because of the core–shell structure, the coating effect leads to a gradual shift of the reaction models toward the 2D nucleation and nucleus growth model (A2), thereby indicating a reduction in nucleation centers for decomposition. , …”

“…Because of the core−shell structure, the coating effect leads to a gradual shift of the reaction models toward the 2D nucleation and nucleus growth model (A2), thereby indicating a reduction in nucleation centers for decomposition. 21,34 As for the reactivity of AP in AHFPs, the decomposition kinetic parameters and models are also obtained. The decomposition of raw AP shows two steps from the TG-DSC curves, whereas the decomposition step of AP in AHFPs composites is gradually decreased to one step.…”