The
Fenton reaction plays a fundamental role in advanced oxidation
processes for the degradation of organic pollutants. Here, we report
the high activity and durability of the CuO–Fe3O4 tube catalyst in the decomposition of organic matter via
a heterogeneous Fenton-like process. The catalytic activity of the
prepared catalysts is evaluated by the degradation of commonly used
organic dyes, methylene blue (MB) and methyl orange (MO). The CuO–Fe3O4 tube catalyst is prepared by the electrospinning
method, which is capable of large-scale synthesis. The synthesized
catalyst is characterized by scanning electron microscopy (SEM), energy-dispersive
X-ray spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron
spectroscopy (XPS), which confirms a tube-like structure of CuO having
an inner wall decorated with Fe3O4. The CuO–Fe3O4 tube catalyst promotes the MB and MO degradation
reaction compared with the conventional CuO particle catalyst. The
improved degradation rate originates from the (1) high utilization
of active sites (Cu(I) and Fe(II)) for generating reactive •OH radicals and (2) efficient regeneration of active Fe(II) by Cu(I)
inside the tube. The SEM analysis after the reaction confirms the
high durability of the CuO–Fe3O4 tube
catalyst. The unique tube-like structure with the coexistence of CuO
and Fe3O4 proves to be a valid strategy to accelerate
the heterogeneous Fenton-like process for removing organic pollutants
from wastewater.