Tuning the bonding dimensions for coordination polymers based on rare earth metal ions

Zhou, Juan; Takata, Yasuyuki; Tang, Si si; He, Xiao Ming; Zhang, Xin Lei; Zhou, Lian; Sun, Lin; Zhang, Jun

doi:10.1039/d2ce01131j

Cited by 2 publications

(2 citation statements)

References 27 publications

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“…These results revealed that the thermal stabilities of 1 , 2 , and 3 reached ca. 275, 200, and 190 °C, respectively, compared to the other CPs. , …”

Section: Resultsmentioning

confidence: 87%

“…However, metal ions possess an analogous behavior and can tune the material dimensions. For example, Eu 3+ , Ho 3+ , and Tb 3+ can be used to construct CPs and produce 1-, 2-, and 3-dimensional frameworks, respectively . When double (or greater) ligands synergistically coordinate, the target CPs will take on diverse coordination, resulting in miscellaneous structures.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Preparing Coordination Polymers with Acentric–Centric Structural Arrangements Related to SHG Response

Zhou,

Cui,

Zhao

et al. 2024

Inorg. Chem.

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“…These results revealed that the thermal stabilities of 1 , 2 , and 3 reached ca. 275, 200, and 190 °C, respectively, compared to the other CPs. , …”

Section: Resultsmentioning

confidence: 87%

Section: Introductionmentioning

confidence: 99%

Preparing Coordination Polymers with Acentric–Centric Structural Arrangements Related to SHG Response

Zhou,

Cui,

Zhao

et al. 2024

Inorg. Chem.

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Synthesis, Structural Characterization and Photocatalytic CO2 Reduction Activity of a New Gd(III) Coordination Polymer with 6-Phenylpyridine-2-carboxylic acid and 4,4’-Bipyridine Ligands

Tai

Wang

et al. 2023

Bull. Chem. React. Eng. Catal.

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A new Gd(III) coordination polymer, {[Gd(L1)3(H2O)2]∙L2}n (1) (HL1 = 6-phenylpyridine-2-carboxylic acid, L2 = 4,4’-bipyridine) was synthesized using 6-phenylpyridine-2-carboxylic acid, 4,4’-bipyridine, NaOH and GdCl3∙6H2O. The structure of Gd(III) coordination polymer has been characterized by IR and X-ray single crystal diffraction. The result of single crystal analysis indicates that fundamental unit of Gd(III) coordination polymer contains one Gd(III) ion, three L1 ligands, two coordinated water molecules and one uncoordinated 4,4’-bipyridine. In 1, the Gd(III) ion is eight-coordinated and surrounded by six O atoms from three L1 ligands and two O atoms from two coordinated water molecules, respectively. The complex 1 exhibits 1D chained structure by the bridging interactions of two carboxyl-oxygen atoms and O−H∙∙∙N hydrogen bonds interactions. The 1D chains are further connected by - stacking interactions to form 3D network architecture. The photocatalytic CO2 reduction activity of complex 1 has also been investigated. The complex 1 exhibits good CO2 reduction activity. With the increase of time, the yield of CO from 18.2 mmol/g in the first hour to 60.3 mmol/g in the third hour. And the CO selectivity has reached 100%. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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Tuning the bonding dimensions for coordination polymers based on rare earth metal ions

Abstract: The structures of targeted coordination polymers (CPs) are strongly affected by various factors: ligands, ions, and synthetic conditions. Herein, the rare earth metal ions Eu3+, Ho3+, and Tb3+ were introduced...

Cited by 2 publications

References 27 publications

Preparing Coordination Polymers with Acentric–Centric Structural Arrangements Related to SHG Response

Preparing Coordination Polymers with Acentric–Centric Structural Arrangements Related to SHG Response

Synthesis, Structural Characterization and Photocatalytic CO2 Reduction Activity of a New Gd(III) Coordination Polymer with 6-Phenylpyridine-2-carboxylic acid and 4,4’-Bipyridine Ligands

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